123 | 0 | 52 |
下载次数 | 被引频次 | 阅读次数 |
利用光学显微镜(OM)、扫描电子显微镜(SEM)、能谱分析仪(EDS)、万能拉伸实验机、显微硬度计及摩擦磨损实验机,研究了稀土La变质及热处理对ZL101合金微观组织、力学性能和耐磨性能的影响.结果表明:稀土La变质可以实现ZL101合金中的α-Al相及共晶Si相的细化,使合金组织形态得到有效改善;对ZL101-0.6%La合金进行T6热处理后,合金组织内的α-Al相及共晶Si相得到进一步细化,α-Al相向等轴晶转变,Si相向细小圆球颗粒状转变;T6态ZL101-0.6%La合金的抗拉强度、伸长率及维氏硬度分别为232.85 MPa, 8.1%及115.7,与ZL101合金基体相比,分别提高了54%,88.37%及48.52%;ZL101合金基体的磨损形式主要包括严重的粘着磨损及磨粒磨损,而T6态ZL101-0.6%La合金的磨损形式主要是轻微的磨粒磨损,稀土La变质及热处理显著提高了合金的耐磨性能,与ZL101合金基体相比,磨损率降低了62.88%.
Abstract:The effects of rare earth element La and heat treatment on the microstructure, mechanics and wear resistance of ZL101 alloy have been investigated by optical microscope(OM), scanning electron microscope(SEM), energy spectrum analyzer(EDS), universal tensile testing machine, microhardness tester and friction and wear testing machine. The results show that rare earth La modification can refine α-Al phase and eutectic Si phase, and improve the microstructure of ZL101 alloy effectively. After T6 heat treatment of ZL101-0.6%La alloy, the α-Al phase and eutectic Si phase morphology are further refined, the α-Al transforms into equiaxed crystals, and the Si transforms into fine spherical particles. The tensile strength, elongation, and Vickers hardness of T6 treated ZL101-0.6%La alloys are 232.85 MPa, 8.1%, and 115.7 respectively, which are 54%, 88.37%, and 48.52% higher than those of ZL101 alloy matrix. The wear modes of ZL101 alloy matrix mainly include severe adhesive wear and abrasive wear, while the wear form of T6 treated ZL101-0.6%La alloy is mainly slightly abrasive wear. Rare earth La and heat treatment significantly improve the wear resistance of ZL101 alloy, and the wear rate is reduced by 62.88%, compared with that of the ZL101 alloy matrix.
[1] 郭红丽,李勇.半固态挤压铸造下稀土Y强化机械零件用ZL105铝合金的制备与性能[J].材料与冶金学报,2022,21(6):442-447.(Guo Hongli,Li Yong.Preparation and properties of semi?solid squeeze casting rare earth Y reinforced ZL105 aluminum alloy for mechanical parts[J].Journal of Materials and Metallurgy,2022,21(6):442-447.)
[2] 薛利文,周文强,朴一男,等.挤压铸造及热处理对Al-Si系合金组织及性能的影响进展[J].特种铸造及有色合金,2021,41(7):842-848.(Xue Liwen,Zhou Wenqiang,Piao Yinan,et al.Progress in effects of squeeze casting process parameters and heat treatment on microstructure and properties of Al-Si alloy[J].Special Casting & Nonferrous Alloys,2021,41(7):842-848.)
[3] 姬旺勤,王晓兵,周亚坤,等.电磁搅拌对Sr变质体育器材用铝基复合材料的影响[J].金属热处理,2023,48(7):217-222.(Ji Wangqin,Wang Xiaobing,Zhou Yakun,et al.Effect of electromagnetic stirring on Sr modified aluminum matrix composites for sports equipment[J].Heat Treatment of Metals,2023,48(7):217-222.)
[4] 董衍蘅,贾志宏,温柏杨,等.稀土Sm对Al-7Si-0.3Mg合金微观组织的影响[J].中国有色金属学报,2020,30(3):479-488.(Dong Yanheng,Jia Zhihong,Wen Baiyang,et al.Effect of rare earth Sm on microstructure of Al-7Si-0.3Mg aluminum alloy[J].The Chinese Journal of Nonferrous Metals,2020,30(3):479-488.)
[5] 陈媛媛,王社则,田博彤.稀土Er对汽车轮毂用A356合金组织与力学性能的影响[J].金属热处理,2019,44(11):39-44.(Chen Yuanyuan,Wang Sheze,Tian Botong.Effect of rare earth Er on microstructure and mechanical properties of A356 alloy for automotive hub[J].Heat Treatment of Metals,2019,44(11):39-44.)
[6] 刘文祎,徐聪,刘茂文,等.稀土元素Gd对Al-Si-Mg铸造合金微观组织和力学性能的影响[J].材料工程,2019,47(6):129-135.(Liu Wenyi,Xu Cong,Liu Maowen,et al.Effect of rare earth element Gd on microstructure and mechanical properties of Al-Si-Mg cast alloy[J].Journal of Materials Engineering,2019,47(6):129-135.)
[7] 于小健,宁萌,周文军,等.稀土Y变质对Al-7Si-0.35Mg合金中富铁相的影响机制[J].兵器材料科学与工程,2018,41(1):38-42.Yu Xiaojian,Ning Meng,Zhou Wenjun,et al.Influence mechanism of rare earth yttrium modification on Fe-rich phase in Al-7Si-0.35Mg alloy[J].Ordnance Material Science and Engineering,2018,41(1):38-42.
[8] 胡凯亮,陈炜晔,李弘怿,等.ADC-12再生铝合金稀土Y变质作用研究[J].真空科学与技术学报,2022,42(3):193-200.(Hu Kailiang,Chen Weiye,Li Hongyi,et al.Modification effect of rare earth Y on ADC-12 recycled aluminum alloy[J].Chinese Journal of Vacuum Science and Technology,2022,42(3):193-200.)
[9] Song X C,Yan H,Zhang X J.Microstructure and mechanical properties of Al-7Si-0.7Mg alloy formed with an addition of (Pr+Ce)[J].Journal of Rare Earths,2017,35(4):412-418.
[10] 张莉,曾敏,王细洋,等.CNTs含量对Al-Zn-Mg-Cu合金的干滑动摩擦磨损的影响[J].兵器材料科学与工程,2021,44(5):71-76.(Zhang Li,Zeng Min,Wang Xiyang,et al.Effect of CNTs content on dry sliding friction and wear of Al-Zn-Mg-Cu alloy[J].Ordnance Material Science and Engineering,2021,44(5):71-76.)
[11] 陈晖,周烨,曾敏,等.混合稀土(Pr+Ce)变质处理ZL105铝合金摩擦磨损性能研究[J].稀有金属与硬质合金,2022,50(4):71-76.(Chen Hui,Zhou Ye,Zeng Min,et al.Study on the friction and wear properties of ZL105 aluminum alloy modified by mixed rare earth(Pr+Ce)[J].Rare Metals and Cemented Carbides,2022,50(4):71-76.)
[12] Yu B B,Yan H,Zhu J B,et al.Effects of La on microstructure and corrosion behavior of AlSi5Cu1Mg alloy[J].Acta Metallurgica Sinica (English Letters),2019,32(4):443-451.
[13] 吴昊,刘旻.耐腐蚀摩托艇ADC12-0.5La铝合金微观组织及制备[J].中国冶金,2022,32(11):135-141.(Wu Hao,Liu Min.Microstructure and preparation of ADC12-0.5La aluminum alloy for corrosion resistant motor boat[J].China Metallurgy,2022,32(11):135-141.)
[14] 唐鹏,刘裔源,陈寒冰,等.稀土熔剂对铝熔体及其合金力学性能的影响[J].机床与液压,2020,48(22):45-49.(Tang Peng,Liu Yiyuan,Chen Hanbing,et al.Effect of rare earth flux on aluminum melt and alloy properties[J].Machine Tool & Hydraulics,2020,48(22):45-49.)
[15] 吴顺意,葛富彪,甘培原,等.La和Ce对铸造Al-7Si-0.6Cu-0.8Fe合金组织及性能的影响[J].特种铸造及有色合金,2023,43(4):529-535.(Wu Shunyi,Ge Fubiao,Gan Peiyuan,et al.Effects of La and Ce on the microstructure and properties of cast Al-7Si-0.6Cu-0.8Fe alloy[J].Special Casting &Nonferrous Alloy,2023,43(4):529-535.)
[16] 姜博,吉泽升,胡茂良,等.固溶时间对ADC12铝合金挤压铸造组织及力学性能的影响[J].中国有色金属学报,2019,29(2):223-231.(Jiang Bo,Ji Zesheng,Hu Maoliang,et al.Effect of solution time on microstructure and mechanical properties of ADC12 aluminum alloy by squeeze casting[J].The Chinese Journal of Nonferrous Metals,2019,29(2):223-231.)
[17] 赵天佑,郭二军,冯义成,等.铸态和T6热处理Al-Si-Cu-Ni-Ce-Cr铸造耐热铝合金的组织和力学性能[J].材料研究学报,2019,33(8):588-596.(Zhao Tianyou,Guo Erjun,Feng Yicheng,et al.Microstructure and mechanical properties of as cast and heat-treated Al-Si-Cu-Ni-Ce-Cr[J].Chinese Journal of Materials Research,2019,33(8):588-596.)
[18] 毛丰,欧黎明,乔永枫,等.Eu和P复合变质对过共晶Al-Si合金微观组织和耐磨性能的影响[J].稀有金属,2021,45(4):393-400.(Mao Feng,Ou Liming,Qiao Yongfeng,et al.Microstructure and wear resistance of hypereutectic Al-Si alloy with combined Eu and P additions[J].Chinese Journal of Rare Metals,2021,45(4):393-400.)
[19] Yang L J.Wear coefficient equation for aluminium-based matrix composites against steel disc[J].Wear,2003,255(1/2/3/4/5/6):579-592.
基本信息:
DOI:10.14186/j.cnki.1671-6620.2025.02.011
中图分类号:TG146.21
引用信息:
[1]张书维,牛子帆,王琳等.稀土La对ZL101铝合金组织、力学性能及磨损性能的影响[J].材料与冶金学报,2025,24(02):176-181.DOI:10.14186/j.cnki.1671-6620.2025.02.011.
基金信息:
国家自然科学基金项目(52074239); 江苏安全技术职业学院校级自然科学重点项目(14589202301)